The Executive’s Loveseat decoration can be dropped from Gatekeeper’s Stronghold PacksUltimate Cartel Packs, which were released on the Cartel Market and bought with Cartel Coins. Cartel Packs, including the Gatekeeper’s Stronghold PackUltimate Cartel Pack, include a random selection of items from the Gatekeeper’s Stronghold Ultimate Cartel collection of items. You aren't guaranteed to get an Executive’s Loveseat decoration from a Gatekeeper’s Stronghold PackUltimate Cartel Pack, but it is one of the few ways to get an Executive’s Loveseat deco apart from buying it on the GTN from another player.
If you're looking to get a Executive’s Loveseat, the easiest way to get it is to head to the Galactic Trade Network (GTN) in SWTOR and buy it with credits from another player. If it's very rare and not available on the Cartel Market, you could try buying from the GTN and hope you get it.